Dense Hydroxyapatite-Zirconia Ceramic Composites with High Strength for Biological Applications

2001 ◽  
Vol 13 (3) ◽  
pp. 214-216 ◽  
Author(s):  
Z. J. Shen ◽  
E. Adolfsson ◽  
M. Nygren ◽  
L. Gao ◽  
H. Kawaoka ◽  
...  
ChemInform ◽  
2010 ◽  
Vol 32 (21) ◽  
pp. no-no ◽  
Author(s):  
Zhijian Shen ◽  
Erik Adolfsson ◽  
Mats Nygren ◽  
Lian Gao ◽  
Hirokazu Kawaoka ◽  
...  

Author(s):  
W. Braue ◽  
R.W. Carpenter ◽  
D.J. Smith

Whisker and fiber reinforcement has been established as an effective toughening concept for monolithic structural ceramics to overcome limited fracture toughness and brittleness. SiC whiskers in particular combine both high strength and elastic moduli with good thermal stability and are compatible with most oxide and nonoxide matrices. As the major toughening mechanisms - crack branching, deflection and bridging - in SiC whiskenreinforced Al2O3 and Si3N41 are critically dependent on interface properties, a detailed TEM investigation was conducted on whisker/matrix interfaces in these all-ceramic- composites.In this study we present HREM images obtained at 400 kV from β-SiC/α-Al2O3 and β-SiC/β-Si3N4 interfaces, as well as preliminary analytical data. The Al2O3- base composite was hotpressed at 1830 °C/60 MPa in vacuum and the Si3N4-base material at 1725 °C/30 MPa in argon atmosphere, respectively, adding a total of 6 vt.% (Y2O3 + Al2O3) to the latter to promote densification.


2012 ◽  
Vol 727-728 ◽  
pp. 1387-1392 ◽  
Author(s):  
Luan M. Medeiros ◽  
Fernando S. Silva ◽  
Juliana Marchi ◽  
Walter Kenji Yoshito ◽  
Dolores Ribeiro Ricci Lazar ◽  
...  

Zirconium dioxide (zirconia) ceramics are known by its high strength and toughness and titanium dioxide (titania) ceramics has outstanding surface properties. The ceramic composite formed between the two oxides are expected to have advantages of both ceramics, especially when its surface area is increased by pores. In this work, ceramic composites of ZrO2-Y2O3-TiO2were synthesized by coprecipitation and rice starch was added as pore former in 10, 20 and 30 wt%. Powders were cold pressed as cylindrical pellets and sintered at 1500 °C for 01 hour and ceramics were characterized by techniques as Archimedes method for density measurements, X-ray diffraction and scanning electron microscopy. Results showed that pores are inhomogeneously distributed through ceramic bodies.


2006 ◽  
Vol 317-318 ◽  
pp. 163-166
Author(s):  
Guo Jun Zhang ◽  
Hideki Kita ◽  
Naoki Kondo ◽  
Tatsuki Ohji

High strength particulate ceramic composites are in general reinforced by strong dispersoids, such as strong ceramic particles (SiC, TiB2, ZrO2, et al) and strong metallic particles (Mo, W, et al). In this work high strength ceramic composites with in-situ synthesized hexagonal boron nitride (h-BN) have been prepared and characterized. As an example, we manufactured mullite-BN composites by reactive hot pressing (RHP) using aluminum borates (9Al2O3·2B2O3 and 2Al2O3·B2O3) and silicon nitride as starting materials. The obtained material RHPed at 1800°C showed a strength of 540 MPa, which was 1.64 times higher than that of the monolithic mullite ceramics. TEM observation revealed that the composite had an isotropic microstructure with a fine mullite matrix grain size of less than 1 μm and a nano-sized h-BN platelets of about 200 nm in length and 60∼80 nm in thickness. The high strength was suggested to be from the reduced matrix grain size and the small toughening effect by the h-BN platelets. In addition, this kind of ceramic composite demonstrates low Young’s modulus that is beneficial to the thermal/mechanical shock resistance, and excellent machinability.


2001 ◽  
Vol 702 ◽  
Author(s):  
Nina A. Orlovskaya ◽  
Jakob Kuebler ◽  
Vladimir I. Subotin ◽  
Mykola Lugovy

ABSTRACTMultilayered ceramic composites are very promising materials for different engineering applications. Laminates with strong interfaces can provide high apparent fracture toughness and damage tolerance along with the high strength and reliability. The control over the mechanical behavior of laminates can be obtained through design of residual stresses in separate layers. Here we report a development of tough silicon nitride based layered ceramics with controlled compressive and tensile stresses in separate layers. We design laminates in a way to achieve high compressive residual stresses in thin (100-150 micron) Si3N4 layers and low tensile residual stresses in thick (600-700 micron) Si3N4-TiN layers. The residual stresses are controlled by the amount of TiN in layers with residual tensile stresses and the layers thickness. The fracture toughness of pure Si3N4(5wt%Y2O3+2wt%Al2O3) ceramics was measured to be of 5 MPa m1/2, while the apparent fracture toughness of Si3N4/Si3N4-TiN laminates was in the range of 7-8 MPa m1/2 depending on the composition and thickness of the layers.


Author(s):  
T. Sornakumar ◽  
M.V. Gopalakrishnan ◽  
V.E. Annamalai ◽  
R. Krishnamurthy ◽  
C.V. Gokularathnam

1991 ◽  
Vol 250 ◽  
Author(s):  
Arthur W. Moore

The development of new and improved ceramic fibers has spurred the development and application of ceramic composites with improved strength, strength/weight ratio, toughness, and durability at increasingly high temperatures. For many systems, the ceramic fibers can be used without modification because their properties are adequate for the chosen application. However, in order to take maximum advantage of the fiber properties, it is often necessary to coat the ceramic fibers with materials of different composition and properties. Examples include (1) boron nitride coatings on a ceramic fiber, such as Nicalon silicon carbide, to prevent reaction with the ceramic matrix during fabrication and to enhance fiber pullout and increase toughness when the ceramic composite is subjected to stress[l]; (2) boron nitride coatings on ceramic yarns, such as Nicalon for use as thermal insulation panels in an aerodynamic environment, to reduce abrasion of the Nicalon and to inhibit the oxidation of free carbon contained within the Nicalon[2]; and (3) ceramic coatings on carbon yarns and carbon-carbon composites to permit use of these high-strength, high-temperature materials in oxidizing environments at very high temperatures[3,4].


2013 ◽  
Vol 2013 (0) ◽  
pp. 93-94
Author(s):  
Takuya Nakamura ◽  
Shinji Taguchi ◽  
Kousei Ijichi ◽  
Yoshikazu Maeda ◽  
Ayako Nagase ◽  
...  

2014 ◽  
Vol 575 ◽  
pp. 214-218
Author(s):  
Huang Jan Hsu ◽  
Shyh Yuan Lee ◽  
Cho-Pei Jiang

The aim of this study is to develop a novel maskless-curing slurry stereolithograhy and sintering process which can fabricate high strength ceramic parts. Three dimension printing of additive manufacturing method was used. High performance stereolithography slurry, which was composed of zirconia powder as structure material and methanol as a solvent and a dispersant, could be prepared with colloidal processing. During layer casting, the diaphanous slurry can penetrate into pores of the subjacent layers. After drying, the binder in the penetrated liquid could connect the fresh layer and subjacent layers. Eventually, a gel-like green block could be built layer by layer. In the exposed region, the resin contained in the green block was cured to connect the zirconia powders to be a part of the rigid green part. The obtained rigid green part was then heated up to 300°C for binder burnout, and then sintered at 1350°C to obtain a high dense zirconia ceramic part. The proposed method of maskless-curing slurry was briefly described and it was proved that the good capacity of solidifying thin layer.


2007 ◽  
Vol 336-338 ◽  
pp. 1155-1158 ◽  
Author(s):  
Hee Seung Kim ◽  
Mi Young Seo ◽  
Ik Jin Kim

Advanced engineering ceramic technology has very remarkable reputation in the high-tech fields such as semiconductor device manufacturing. ZTA (Zirconia Toughened Alumina), ruby and alumina is applied in the manufacturing of the capillaries that demonstrate high strength, fracture toughness and long life. The advantages of the new composite material over the standard ultra-fine grain high-density material have been proven in many applications especially for packages requiring less than 50μm capillary tip diameter. In this work, micro-structural evolution of ceramic composites and its correlation with important criteria in the selection of the suitable capillary material either ZTA composites or high-density ruby ceramics for a specific package applications will be discussed.


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